Analysis of phase diagrams employing Bayesian excess parameter estimation
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Königsberger, E.
ORCID: 0000-0002-4606-0741 and Gamsjäger, H.
(1990)
Analysis of phase diagrams employing Bayesian excess parameter estimation.
Monatshefte für Chemie Chemical Monthly, 121
(2-3).
pp. 119-127.
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Abstract
Bayesian estimation of thermodynamic excess quantities was applied to liquidus data of the systems cyclohexane — benzene and potassium chloride — sodium chloride as well as data on the austenite ferrite equilibrium of the iron — zinc system. Theoretical considerations (KCl-NaCl) and results from calorimetric or partial pressure studies (Fe-Zn) were used as independenta priori information. The recalculated phase diagrams coincide perfectly with those given in the literature. In each case the thermodynamic significance of the experimental data is discussed.
| Item Type: | Journal Article |
|---|---|
| Publisher: | Springer-Verlag |
| Copyright: | © Springer-Verlag 1990 |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/6516 |
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