Regioselectivity in the reactions of methoxydehydrobenzenes with furans. Part 2. 2-Methoxyfuran and methoxydehydrobenzenes
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Giles, R.G.F., Hughes, A.B. and Sargent, M.V. (1991) Regioselectivity in the reactions of methoxydehydrobenzenes with furans. Part 2. 2-Methoxyfuran and methoxydehydrobenzenes. Journal of the Chemical Society, Perkin Transactions 1 (6). pp. 1581-1587.
Link to Published Version: http://dx.doi.org/10.1039/P19910001581
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Abstract
Acid-induced ring opening of adducts of furan and methoxydehydrobenzenes gives the naphthalenols derived from the more stable carbocation. The cycloadditions of methoxydehydrobenzenes containing a 3-methoxy group and 2-methoxyfuran are highly regiospecific. The adducts, being strained acetals, undergo ring opening to provide a convenient synthesis of naphthalenols.
| Item Type: | Journal Article |
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| Murdoch Affiliation(s): | School of Mathematical and Physical Sciences |
| Publisher: | Royal Society of Chemistry |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/35757 |
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