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Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII)

Rosseinsky, D.R. and Nicol, M.J.ORCID: 0000-0002-8757-161X (1970) Electron transfer reactions of vanadium(IV) with some oxyanion oxidants in aqueous perchloric acid. Part I. Reaction with chromium-(VI) and manganese(VII). Journal of the Chemical Society A: Inorganic, Physical, Theoretical . pp. 1196-1200.

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Abstract

The rate law k[CrVI][VIV]2[H+]n/VV], with n < 1, is confirmed, and differences from the iron(II)–chromium(IV) result are explained. With proper interpretation the comparability of iron(II) with vanadium(IV) reactions is preserved. The reaction of vanadium(IV) with manganese(VIII) appears to be initially just of the second order, but non-stoicheiometry and acceleration by product manganese(II) introduce later complications only qualitatively resolvable.

Item Type: Journal Article
Publisher: Royal Society of Chemistry
Copyright: 1970 RSC
URI: http://researchrepository.murdoch.edu.au/id/eprint/29826
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