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Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution

Rosseinsky, D.R. and Nicol, M.J.ORCID: 0000-0002-8757-161X (1965) Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution. Transactions of the Faraday Society, 61 . p. 2718.

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Abstract

The reaction 4MnIIfMnVxI = 5MnIII obeyed the rate equation, rate = k[Mnu]2[MnvII]. In lithium perchlorate media the [H+]-dependence was found to be k = k~H+]+ko. Activation energies and entropies were compared with standard values for formation of intermediate species in an examination of possible mechanisms.

Item Type: Journal Article
Publisher: Royal Society of Chemistry
Copyright: 1965 RSC
URI: http://researchrepository.murdoch.edu.au/id/eprint/29821
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