Anion-specific partitioning in two-phase finite volume systems: Possible implications for mechanisms of ion pumps
Boström, M., Lima, E.R.A., Biscaia, E.C., Tavares, F.W., Nostro, P.L., Parsons, D.F.ORCID: 0000-0002-3956-6031, Deniz, V. and Ninham, B.W.
(2009)
Anion-specific partitioning in two-phase finite volume systems: Possible implications for mechanisms of ion pumps.
The Journal of Physical Chemistry B, 113
(23).
pp. 8124-8127.
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Abstract
In two-phase finite volume systems of electroneutral phospholipids, the electrolyte concentration is different in the two phases. The partitioning is highly anion-specific, a phenomenon not accounted for by classical electrolyte theories. It is explained if ionic dispersion forces that lead to specific ion binding are taken into account. The mechanism provides a contribution to active ion pumps not previously considered
Item Type: | Journal Article |
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Publisher: | American Chemical Society |
Copyright: | © 2009 American Chemical Society. |
URI: | http://researchrepository.murdoch.edu.au/id/eprint/27341 |
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