Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions
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Rowland, D. (2015) Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions. Talanta, 144 . pp. 90-92.
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Link to Published Version: http://dx.doi.org/10.1016/j.talanta.2015.05.050
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Abstract
Pitzer equations are widely employed to correlate and predict the volumetric properties of aqueous electrolyte solutions over broad ranges of pressure and temperature. However, the currently-used pressure and temperature terms are empirical and tend to violate known thermodynamic behaviour. Three functional constraints have been identified that overcome this problem.
| Publication Type: | Journal Article |
|---|---|
| Murdoch Affiliation: | School of Engineering and Information Technology |
| Publisher: | Elsevier BV |
| Copyright: | © 2015 Elsevier B.V. |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/27309 |
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