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Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures

Singh, P., MacLeod, I.D. and Parker, A.J. (1984) Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures. Journal of Solution Chemistry, 13 (2). pp. 103-119.

Link to Published Version: http://dx.doi.org/10.1007/BF00646043
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Abstract

The limiting conductance of various salts of Na+, Ag+, Cu+, Cu2+ and Ph4As+ in acetonitrile-water (AN-H2O) and pyridine-water (Py-H2O) mixtures are reported. Single ion values are calculated for AN-H2O mixtures using the TATB assumption [λo(Ph4As+) = λo(Ph4B-)]. The trends observed for the limiting Walden products (λoη) of the electrolytes and individual ions are discussed in terms of specific ion-solvent interactions and the structural effects of the solvent mixtures.

Item Type: Journal Article
Murdoch Affiliation: School of Mathematical and Physical Sciences
Publisher: Springer Netherlands
Copyright: © 1984 Plenum Publishing Corporation.
URI: http://researchrepository.murdoch.edu.au/id/eprint/21103
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