Asymmetric syntheses of Isochroman-4,7-diols through intramolecular cyclization of tethered lactaldehydes
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Giles, R.G.F., Green, I.R., Gruchlik, Y. and Oosthuizen, F.J. (2000) Asymmetric syntheses of Isochroman-4,7-diols through intramolecular cyclization of tethered lactaldehydes. Australian Journal of Chemistry, 53 (4). pp. 341-347.
Link to Published Version: http://dx.doi.org/10.1071/CH00020
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Abstract
Ready cyclization through silica gel chromatography of the asymmetric phenolic lactaldehyde (14) afforded the diastereomeric pair of isochroman-4,7-diols (21) and (23) in good yield, while (17), the benzylic epimer of (14), similarly yielded the isochroman-4,7-diol (25) as a single diastereomer.
| Item Type: | Journal Article |
|---|---|
| Murdoch Affiliation(s): | School of Chemical and Mathematical Science |
| Publisher: | Commonwealth Scientific and Industrial Research Organization Publishing |
| Copyright: | © 2000 CSIRO |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/17426 |
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