Fluoride complexes of the alkali metal ions
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Chan, C.B., Tioh, N.H. and Hefter, G.T. (1984) Fluoride complexes of the alkali metal ions. Polyhedron, 3 (7). pp. 845-851.
Link to Published Version: http://dx.doi.org/10.1016/S0277-5387(00)84633-1
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Abstract
Measurements by fluoride ion-selective electrode potentiometry on the very weak monofluoride complexes of the alkali metal ions in aqueous solution at 25°C and an ionic strength of 1M indicate their stability constants lie in the order Li+ > Na+ > K+ > Rb+ ⋍ Cs+. Data at varying ionic strengths and temperatures were used to calculate infinite dilution stability constants and enthalpies and entropies of complexation for LiF and NaF.
| Item Type: | Journal Article |
|---|---|
| Murdoch Affiliation(s): | School of Mathematical and Physical Sciences |
| Publisher: | Elsevier |
| Copyright: | © 1984 Elsevier Ltd. |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/13567 |
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