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Fluoride complexes of the alkali metal ions

Chan, C.B., Tioh, N.H. and Hefter, G.T. (1984) Fluoride complexes of the alkali metal ions. Polyhedron, 3 (7). pp. 845-851.

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Measurements by fluoride ion-selective electrode potentiometry on the very weak monofluoride complexes of the alkali metal ions in aqueous solution at 25°C and an ionic strength of 1M indicate their stability constants lie in the order Li+ > Na+ > K+ > Rb+ ⋍ Cs+. Data at varying ionic strengths and temperatures were used to calculate infinite dilution stability constants and enthalpies and entropies of complexation for LiF and NaF.

Item Type: Journal Article
Murdoch Affiliation(s): School of Mathematical and Physical Sciences
Publisher: Elsevier
Copyright: © 1984 Elsevier Ltd.
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