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Does [A1F6]3- exist in aqueous solution?

Hefter, G., Odor, A.B. and Tóth, I. (2000) Does [A1F6]3- exist in aqueous solution? Australian Journal of Chemistry, 53 (7). pp. 625-626.

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High-field 19F n.m.r. measurements in Me4NF solutions at 278 K confirm the existence of [AlFi](3-i)+ complexes for i ≤ 5 but indicate that the widely assumed [A1F6]3- does not form at significant concentrations in aqueous solution even at very high F-/AlIII ratios.

Item Type: Journal Article
Murdoch Affiliation(s): School of Chemical and Mathematical Science
Publisher: Commonwealth Scientific and Industrial Research Organization Publishing
Copyright: © CSIRO 2000.
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