Electrochemical behavior of LiFePO 4 in aqueous lithium hydroxide electrolyte
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Manickam, M.
ORCID: 0000-0001-6558-8317, Singh, P., Issa, T.B.ORCID: 0000-0003-0913-3857, Thurgate, S. and Prince, K.
(2006)
Electrochemical behavior of LiFePO 4 in aqueous lithium hydroxide electrolyte.
Key Engineering Materials, 320
.
pp. 271-274.
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Abstract
The electrochemistry of olivine-type iron phosphate (FePO 4) as a battery cathode material, in aqueous lithium hydroxide (LiOH), has been investigated. The material forms intercalated LiFePO 4 reversibly on electroreduction/oxidation. The formation of Fe 3O 4 phase, in addition to the regeneration of FePO 4 during reverse oxidation of LiFePO 4, also occurs. In this regard, the mechanism of FePO 4 discharge/charge in aqueous LiOH differs from that in non-aqueous solvents.
| Item Type: | Journal Article |
|---|---|
| Murdoch Affiliation: | School of Chemical and Mathematical Science |
| Publisher: | Trans Tech Publications |
| Copyright: | © 2006 Trans Tech Publications, Switzerland |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/11551 |
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