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Viscosity B-coefficients, structural entropies and heat capacities, and the effects of ions on the structure of water

Marcus, Y. (1994) Viscosity B-coefficients, structural entropies and heat capacities, and the effects of ions on the structure of water. Journal of Solution Chemistry, 23 (7). pp. 831-848.

Link to Published Version: http://dx.doi.org/10.1007/BF00972677
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Abstract

The water-structural contributions to the entropies and heat capacities of hydration of over 120 ions and the viscosity B-coefficients of nearly 80 aqueous ions are tabulated and correlated. B-coefficients for many more ions are predicted from this relationship and from their dependence on ionic size and charge. The structural entropies determine a unique scale of water structure making and breaking by the ions.

Publication Type: Journal Article
Murdoch Affiliation: School of Mathematical and Physical Sciences
Publisher: Springer Netherlands
Copyright: © 1994 Plenum Publishing Corporation.
URI: http://researchrepository.murdoch.edu.au/id/eprint/35922
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