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Reaction of o-hydroxyphenyl alkyl ketones with phosphorus trichloride. Formation of 1,3,2-dioxaphosphorinans viaα-proton abstraction

Cragg, G.M.L., Davidowitz, B., Giles, R.G.F. and Haines, R.J. (1977) Reaction of o-hydroxyphenyl alkyl ketones with phosphorus trichloride. Formation of 1,3,2-dioxaphosphorinans viaα-proton abstraction. Journal of the Chemical Society, Chemical Communications (16). pp. 569-570.

Link to Published Version: http://dx.doi.org/10.1039/C39770000569
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Abstract

Treatment of PCl3 with o-HOC6H4COCH2R (R = H or Et) and NEt3 affords 2-chloro-1,3,2-dioxaphosphorinans, which can be readily converted into the corresponding 2-alkoxy derivatives; evidence is presented for the formation of analogous derivatives on similar reaction of acetylacetone and PCl3.

Publication Type: Journal Article
Publisher: Chemical Society
Copyright: 1977 Royal Society of Chemistry
URI: http://researchrepository.murdoch.edu.au/id/eprint/35596
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