Partial Molar Volumes of Cyclic Ketones at Infinite Dilution in Water at TemperaturesT= (278 to 373) K and Low Pressure†
Cibulka, I., Šimurka, L. and Hnědkovský, L. (2010) Partial Molar Volumes of Cyclic Ketones at Infinite Dilution in Water at TemperaturesT= (278 to 373) K and Low Pressure†. Journal of Chemical & Engineering Data, 55 (12). pp. 5429-5434.
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Density data for dilute aqueous solutions of four cyclic ketones (cyclopentanone, cyclohexanone, cycloheptanone, and cyclohexane-1,4-dione) obtained using both an Anton Paar DSA 5000 vibrating-tube densimeter and a laboratory-made flow densimeter are presented together with partial molar volumes at infinite dilution (standard partial molar volumes) calculated from the measured data. The measurements were performed at temperatures T = (278 to 373) K and at either atmospheric pressure or p = 0.5 MPa. Trends for the homologous series are discussed, and group contributions to the standard partial molar volume are evaluated.
|Publication Type:||Journal Article|
|Publisher:||American Chemical Society|
|Copyright:||© 2010 American Chemical Society|
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