The effect of synthesis gas on the performance of Ni-based solid oxide fuel cells
Drewery, M., Stockenhuber, M., Kennedy, E. and Dlugogorski, B. (2014) The effect of synthesis gas on the performance of Ni-based solid oxide fuel cells. In: CHEMECA 2014, 28 September - 1 October, Perth, Western Australia
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An increased interest in using hydrocarbons in solid oxide fuel cells for the production of power has led to research into operation on synthesis (syn) gas, a mixture of hydrogen and carbon monoxide. Hydrocarbons are typically reformed, either internally or in an external reformer prior to the fuel cell, producing syngas with various H2:CO ratios depending on the hydrocarbon used. This paper examines the effect of varying the H2:CO ratio with respect to C1 to C4 steam reforming reactions and additionally a mixture containing a higher ratio of carbon monoxide. It was found that there was no significant relationship between cell performance and H2:CO ratio. For low flow rates, however, the high carbon monoxide concentration resulted in a significant decrease in cell performance. It was determined that this was caused by reversible carbon deposition as opposed to a decrease in carbon monoxide reactivity.
|Publication Type:||Conference Paper|
|Murdoch Affiliation:||School of Engineering and Information Technology|
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