Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions
Rowland, D. (2015) Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions. Talanta, 144 . pp. 90-92.
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Pitzer equations are widely employed to correlate and predict the volumetric properties of aqueous electrolyte solutions over broad ranges of pressure and temperature. However, the currently-used pressure and temperature terms are empirical and tend to violate known thermodynamic behaviour. Three functional constraints have been identified that overcome this problem.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Engineering and Information Technology|
|Copyright:||© 2015 Elsevier B.V.|
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