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Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions

Rowland, D. (2015) Thermodynamically-robust Pitzer equations for volumetric properties of electrolyte solutions. Talanta, 144 . pp. 90-92.

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Link to Published Version: http://dx.doi.org/10.1016/j.talanta.2015.05.050
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Abstract

Pitzer equations are widely employed to correlate and predict the volumetric properties of aqueous electrolyte solutions over broad ranges of pressure and temperature. However, the currently-used pressure and temperature terms are empirical and tend to violate known thermodynamic behaviour. Three functional constraints have been identified that overcome this problem.

Publication Type: Journal Article
Murdoch Affiliation: School of Engineering and Information Technology
Publisher: Elsevier BV
Copyright: © 2015 Elsevier B.V.
URI: http://researchrepository.murdoch.edu.au/id/eprint/27309
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