Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures
Singh, P., MacLeod, I.D. and Parker, A.J. (1984) Solvation of ions. Part XXIX. Ionic conductances in acetonitrile-water and pyridine-water mixtures. Journal of Solution Chemistry, 13 (2). pp. 103-119.
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The limiting conductance of various salts of Na+, Ag+, Cu+, Cu2+ and Ph4As+ in acetonitrile-water (AN-H2O) and pyridine-water (Py-H2O) mixtures are reported. Single ion values are calculated for AN-H2O mixtures using the TATB assumption [λo(Ph4As+) = λo(Ph4B-)]. The trends observed for the limiting Walden products (λoη) of the electrolytes and individual ions are discussed in terms of specific ion-solvent interactions and the structural effects of the solvent mixtures.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Mathematical and Physical Sciences|
|Copyright:||© 1984 Plenum Publishing Corporation.|
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