Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants
Hefter, G.T. (1989) Solvation of flouride ions. 3. A review of flouride solvation thermodynamics in nonaqueous and mixed solvants. Reviews in Inorganic Chemistry, 10 (1-3). pp. 185-223.
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Thermodynamic data for fluoride salts in non-aqueous and mixed solvents are collected and reviewed. Thermodynamic parameters for the salvation of the fluoride ion have been derived from these data via the tetraphenylarsonium (or phosphonium) tetraphenylborate assumption. Gibbs free energies of transfer of F- from water to pure nonaqueous solvents, obtained mainly from solubility data, often show large discrepancies between independent determinations.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Chemical and Mathematical Science|
|Publisher:||Walter de Gruyter|
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