Analysis of phase diagrams employing Bayesian excess parameter estimation
Königsberger, E. and Gamsjäger, H. (1990) Analysis of phase diagrams employing Bayesian excess parameter estimation. Monatshefte für Chemie Chemical Monthly, 121 (2-3). pp. 119-127.
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Bayesian estimation of thermodynamic excess quantities was applied to liquidus data of the systems cyclohexane — benzene and potassium chloride — sodium chloride as well as data on the austenite ferrite equilibrium of the iron — zinc system. Theoretical considerations (KCl-NaCl) and results from calorimetric or partial pressure studies (Fe-Zn) were used as independenta priori information. The recalculated phase diagrams coincide perfectly with those given in the literature. In each case the thermodynamic significance of the experimental data is discussed.
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|Copyright:||© Springer-Verlag 1990|
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