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Anisotropic molecular reorientation measured by NMR relaxation including cross terms between dipolar and chemical shift anisotropy interactions

Königsberger, E. and Sterk, H. (1985) Anisotropic molecular reorientation measured by NMR relaxation including cross terms between dipolar and chemical shift anisotropy interactions. The Journal of Chemical Physics, 83 (6). pp. 2723-2726.

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Abstract

It will be demonstrated that the chemical shift anisotropy (CSA) relaxation mechanism for protonated aromatic 13C nuclei is by no means negligible. The cross correlation spectral density arising from dipolar and CSA interactions in the natural abundance 13C–H spin system of pentachlorobenzene is included in the complete determination of the molecular motional anisotropy. Additionally, the absolute sign of the indirect coupling constant 1JCH is shown to be positive.

Publication Type: Journal Article
Publisher: American Institute of Physics
Copyright: © 1985 American Institute of Physics
URI: http://researchrepository.murdoch.edu.au/id/eprint/6491
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