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Partial Molar Volumes of Cyclic Ketones at Infinite Dilution in Water at TemperaturesT= (278 to 373) K and Low Pressure†

Cibulka, I., Šimurka, L. and Hnědkovský, L. (2010) Partial Molar Volumes of Cyclic Ketones at Infinite Dilution in Water at TemperaturesT= (278 to 373) K and Low Pressure†. Journal of Chemical & Engineering Data, 55 (12). pp. 5429-5434.

Link to Published Version: http://dx.doi.org/10.1021/je100547a
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Abstract

Density data for dilute aqueous solutions of four cyclic ketones (cyclopentanone, cyclohexanone, cycloheptanone, and cyclohexane-1,4-dione) obtained using both an Anton Paar DSA 5000 vibrating-tube densimeter and a laboratory-made flow densimeter are presented together with partial molar volumes at infinite dilution (standard partial molar volumes) calculated from the measured data. The measurements were performed at temperatures T = (278 to 373) K and at either atmospheric pressure or p = 0.5 MPa. Trends for the homologous series are discussed, and group contributions to the standard partial molar volume are evaluated.

Publication Type: Journal Article
Publisher: American Chemical Society
Copyright: © 2010 American Chemical Society
URI: http://researchrepository.murdoch.edu.au/id/eprint/32066
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