Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution
Rosseinsky, D.R. and Nicol, M.J. (1965) Kinetics and mechanism of the formation of manganese(III) from manganese(II) and (VII) in aqueous perchlorate solution. Transactions of the Faraday Society, 61 . p. 2718.
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The reaction 4MnIIfMnVxI = 5MnIII obeyed the rate equation, rate = k[Mnu]2[MnvII]. In lithium perchlorate media the [H+]-dependence was found to be k = k~H+]+ko. Activation energies and entropies were compared with standard values for formation of intermediate species in an examination of possible mechanisms.
|Publication Type:||Journal Article|
|Publisher:||Royal Society of Chemistry|
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