Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10
Yu, H., Kennedy, E.M., Ong, W-H, Mackie, J.C., Han, W. and Dlugogorski, B.Z. (2008) Experimental and kinetic studies of gas-phase pyrolysis of n-C 4F10. Industrial & Engineering Chemistry Research, 47 (8). pp. 2579-2584.
*Subscription may be required
The gas-phase pyrolysis of n-C4F10 has been studied experimentally in a plug flow, isothermal α-alumina reactor at atmospheric pressure and various residence times over the temperature range of 873 to 1148 K. The major products are C2F6, C2F 4, C3F8, and C3F6 (CF3-CF=CF2). Minor products include Cyclo-C 4F8 (c-C4F8) and CO2. CF4 is detected in trace amounts at high temperatures. A kinetic reaction scheme involving 20 species and 30 reactions is developed and used to model n-C4F10 pyrolysis. A generally satisfactory agreement between experimental and modeling results is obtained on the conversion levels of n-C4F10 and the rates of formation of C2F6 and C3F8.
|Publication Type:||Journal Article|
|Publisher:||American Chemical Society|
|Copyright:||© 2008 American Chemical Society.|
|Item Control Page|