Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
Khan, N.A., Kennedy, E.M., Dlugogorski, B.Z., Adesina, A.A. and Stockenhuber, M. (2014) Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5. Catalysis Communications, 53 . pp. 42-46.
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Synthesis gas (CO + H2) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis gas from CH4, under partial oxidation conditions using N2O as oxidant. With O2 as oxidant over the same Co-ZSM-5 catalyst, cobalt on alumina and Fe-ZSM-5, only COx and H2O are formed. Isolated Co2 + sites in the ZSM-5 support are proposed as the active sites for H2 (synthesis gas) formation.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Engineering and Information Technology|
|Copyright:||© 2014 Elsevier B.V.|
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