Kinetics of the bromate–iodide and iodate–iodide reactions by pH-stat techniques
Barton, A.F.M., Cheong, H.N. and Smidt, R.E. (1976) Kinetics of the bromate–iodide and iodate–iodide reactions by pH-stat techniques. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 72 . pp. 568-574.
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Buffer-free pH-stat methods were applied to kinetic investigations of the iodate-iodide and bromate-iodide reactions in the pH range 3-4 yielding the rate laws v′ = k′0[H+]2[I -]2[IO3-] and v = k0 [H+]2[I-][BrO3-] + k 1[H+][I-][BrO3-]. In addition, for [I-] and [IO3-] of the order of 10-2M (M = mol dm-3) the rate of reaction was 4th order in [I-], 2nd order in [IO3-], and the order with respect to [H+] increased from 1st towards 3rd as [H+] decreased from 8 × 10-7 M to 4 × 10-8 M
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Mathematical and Physical Sciences|
|Publisher:||Faraday Division of the Chemical Society|
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