Gibbs energies of transfer of cations from water to mixed aqueous organic solvents
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A large number of quantitative studies have been made of the Gibbs energy of transfer (the solvent medium effect) for cations transferring from water into mixed aqueous−organic solvent systems, mainly at 25 °C. Nevertheless, no systematic effort appears to have been made to compile and analyze these data, particularly for multivalent cations. A critical review of this information and its presentation in a manner that permits comparison of different cations in a given solvent mixture and of a given cation transferring into different mixtures is therefore of value.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Chemical and Mathematical Science|
|Publisher:||American Chemical Society|
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