Does [A1F6]3- exist in aqueous solution?
Hefter, G., Odor, A.B. and Tóth, I. (2000) Does [A1F6]3- exist in aqueous solution? Australian Journal of Chemistry, 53 (7). pp. 625-626.
*Subscription may be required
High-field 19F n.m.r. measurements in Me4NF solutions at 278 K confirm the existence of [AlFi](3-i)+ complexes for i ≤ 5 but indicate that the widely assumed [A1F6]3- does not form at significant concentrations in aqueous solution even at very high F-/AlIII ratios.
|Publication Type:||Journal Article|
|Murdoch Affiliation:||School of Chemical and Mathematical Science|
|Publisher:||Commonwealth Scientific and Industrial Research Organization Publishing|
|Copyright:||© CSIRO 2000.|
|Item Control Page|