Does [A1F6]3- exist in aqueous solution?
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Hefter, G., Odor, A.B. and Tóth, I. (2000) Does [A1F6]3- exist in aqueous solution? Australian Journal of Chemistry, 53 (7). pp. 625-626.
Link to Published Version: http://dx.doi.org/10.1071/CH00116
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Abstract
High-field 19F n.m.r. measurements in Me4NF solutions at 278 K confirm the existence of [AlFi](3-i)+ complexes for i ≤ 5 but indicate that the widely assumed [A1F6]3- does not form at significant concentrations in aqueous solution even at very high F-/AlIII ratios.
| Publication Type: | Journal Article |
|---|---|
| Murdoch Affiliation: | School of Chemical and Mathematical Science |
| Publisher: | Commonwealth Scientific and Industrial Research Organization Publishing |
| Copyright: | © CSIRO 2000. |
| URI: | http://researchrepository.murdoch.edu.au/id/eprint/1200 |
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