Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents

Hefter, G., Marcus, Y. and Waghorne, W.E. (2002) Enthalpies and entropies of transfer of electrolytes and ions from water to mixed aqueous organic solvents. Chemical Reviews, 102 (8). pp. 2773-2836.

Abstract

A wide-ranging critically evaluated compilation of the standard molar enthalpies and entropies of transfer of electrolytes from water to mixed aqueous-organic solvents were shown. For this compilation, the reported values were recalculated to obtain a consistent format that enabled comparisons to be made among the data. These whole-salt data were then split into the transfer functions of the individual ions, using an appropriate extrathermodynamic assumption.